Equilibrium Constant Equation:
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The equilibrium constant (Keq) equation describes the ratio of product concentrations to reactant concentrations at equilibrium for a chemical reaction. For a general reaction aA + bB ⇌ cC + dD, the equilibrium constant is defined as shown above.
The calculator uses the equilibrium constant equation:
Where:
Explanation: The equation quantifies the position of equilibrium, with larger values favoring products and smaller values favoring reactants.
Details: The equilibrium constant is fundamental in chemical thermodynamics, predicting reaction direction, extent of reaction, and guiding industrial process optimization.
Tips: Enter all concentrations in molarity (M) and stoichiometric coefficients as positive numbers. Ensure concentrations are non-negative values.
Q1: What does a large Keq value indicate?
A: A large Keq (>1) indicates the reaction favors product formation at equilibrium, while a small Keq (<1) favors reactants.
Q2: Is Keq temperature dependent?
A: Yes, Keq varies with temperature according to the van't Hoff equation. It's constant only at a given temperature.
Q3: What are the units of Keq?
A: Keq is typically dimensionless for concentration-based calculations, though it may have units for different equilibrium constant expressions.
Q4: When is Keq undefined?
A: Keq is undefined when any reactant concentration is zero in the denominator, as this would involve division by zero.
Q5: How does Keq relate to Gibbs free energy?
A: ΔG° = -RT ln K, where ΔG° is the standard Gibbs free energy change, R is the gas constant, and T is temperature.