Ka To Kw Equation:
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The Ka To Kw equation calculates the ion product of water (Kw) from the acid dissociation constant (Ka) and base dissociation constant (Kb) of a conjugate acid-base pair. This relationship is fundamental in acid-base chemistry and equilibrium calculations.
The calculator uses the Ka To Kw equation:
Where:
Explanation: For any conjugate acid-base pair, the product of their dissociation constants equals the ion product of water at 25°C (1.0 × 10⁻¹⁴ M²).
Details: Calculating Kw helps determine the relationship between acid and base strengths in conjugate pairs, predict solution pH, and understand acid-base equilibrium behavior in aqueous solutions.
Tips: Enter Ka and Kb values in molar units (M). Both values must be positive and non-zero. The calculator will compute the ion product of water (Kw) in M².
Q1: What is the typical value of Kw at 25°C?
A: At 25°C, Kw = 1.0 × 10⁻¹⁴ M². This value increases with temperature.
Q2: Can this equation be used for any acid-base pair?
A: Yes, the equation applies to any conjugate acid-base pair in aqueous solution at equilibrium.
Q3: How does temperature affect Kw?
A: Kw increases with temperature because the autoionization of water is endothermic. At 37°C, Kw ≈ 2.4 × 10⁻¹⁴ M².
Q4: What if I only know Ka or Kb?
A: If you know one constant, you can calculate the other using Kw = Ka × Kb, provided you know the temperature-dependent Kw value.
Q5: Are there limitations to this equation?
A: The equation assumes ideal behavior and constant temperature. It may be less accurate in concentrated solutions or at extreme temperatures.