Acid Dissociation Constant Formula:
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The acid dissociation constant (Ka) is a quantitative measure of the strength of an acid in solution. For acetic acid, it represents the equilibrium constant for the dissociation reaction: CH₃COOH ⇌ CH₃COO⁻ + H⁺.
The calculator uses the equivalence point method:
Where:
Explanation: At the equivalence point of a weak acid-strong base titration, the pH is determined by the hydrolysis of the conjugate base, allowing calculation of Ka.
Details: Ka values are crucial for understanding acid strength, predicting reaction outcomes, calculating pH of solutions, and designing buffer systems in chemistry and biochemistry.
Tips: Enter the pH measured at the equivalence point and the initial concentration of acetic acid. Ensure pH values are between 0-14 and concentration is positive.
Q1: Why use the equivalence point method?
A: The equivalence point provides a precise moment where the weak acid is completely neutralized, allowing accurate determination of Ka from the resulting pH.
Q2: What is the typical Ka value for acetic acid?
A: Acetic acid has Ka ≈ 1.8 × 10⁻⁵ M, making it a weak acid. The calculated value should be close to this reference.
Q3: How accurate is this method?
A: This method provides good accuracy for monoprotic weak acids when proper titration techniques are used and the equivalence point is clearly identified.
Q4: Can this be used for other weak acids?
A: Yes, this method works for any monoprotic weak acid when titrated with a strong base and the equivalence point pH is measured.
Q5: What affects the accuracy of the calculation?
A: Temperature, ionic strength, precise equivalence point detection, and instrument calibration can all affect the accuracy of the calculated Ka value.